STEP BY STEP INSTRUCTIONS FOR COMPLETING YOUR
ABSTRACT
Abstracts should be 300 words or less.
You may use Microsoft Word or Text format. Keep the same point
size throughout.
Left justify everything. Do not use extra returns.
If using Word, please use superscript, subscript, italics,
bold and underline where appropriate.
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caps unless it is to identify a trade name, registered name or
other name that mandates all caps. In the title of the paper be
sure to capitalize the first letter of each word as needed.
Leave a space between the header information and abstract
proper.
Leave a space between the abstract proper and the information
we need to communicate with you
Keep the abstract text in one paragraph. If literature
citations are needed, insert them in parentheses and not as
footnotes. Credits, if any, should be added at the end of the
abstract, but not as a new paragraph.
If structures or other forms of illustrations are used,
drawings should be part of the overall abstract.
1) Title of Paper. Use correct punctuation at the end.
2) Author's full name using first name first. Use a comma
after the full name.
3) Business name. Use a comma after the business name.
4) Your business mailing address (address, city, state, zip)
5) If more than one author, separate by semi-colon, after each
author's mailing address. Underline the speaker's name if more
than one author.
6) SPACE
7) Abstract
8) SPACE
9) Indicate which symposia you desire to present for
10) Indicate whether oral session or poster session
11) Indicate name, business, mailing address, phone, fax and
e-mail for the primary contact
SAMPLE
Multi-Frequency EPR Analysis of Dipolar and Exchange
Interactions Between Managese and Tyrosine In The S2 Yz
State of Photosystems II. K.V. Lakshmi, Yale University,
Department of Chemistry, New Haven, CT 06520-8107; Sandra S.
Eaton, University of Denver, Department of Chemistry, Denver, CO
80208-2436; Harry A. Frank, University of Connecticut, Department
of Chemistry, Storrs, CT 06269-4060
Acetate-inhibited photosystem II, upon room temperature
illumination, exhibits a 240 G wide X-band EPR signal at 10
K.1 This EPR signal arises from
an interaction between the S2
state of the Mn4 cluster and an
oxidized tyrosine residue, Yz.2 In
the present study, the exchange and dipolar interactions between
the two paramagnetic species are simulated at X and Q-band
frequencies utilizing second-order perturbation theory.3 The positions and relative intensities of
the hyperfine lines in the S = ½ S2
-state multiline EPR signal are accurately simulated
by including g-anisotropy and four sets of axially symmetric
55Mn hyperfine tensors. These
parameters are then used to simulate the dipolar and exchange
interactions giving rise to the broad experimental S2 Yz EPR
signal at X and Q-band frequencies. A precise distance
determination between the Mn4
Cluster and Yz in
the O2-evolving complex better enables us to elucidate the direct
involvement of Yz in
water-oxidation chemistry. Supported by NIH GM32715 and GM36442
(Yale) and NIH GM21156 (Denver).
1. Boussac and Rutherford, Biochem., 1988, 27, 3476.
2. Tang et al., J. Amer. Chem. Soc., 1996, 118, 7638.
3. Eaton et al., J. Magn. Res., 1983, 52, 435.
EPR Symposia
Oral Session
Sandra Eaton, University of Denver, Department of Chemistry
& Biochemistry, Denver, CO 80208-2436, phone 303-871-3102, fax
303-871-2254, seaton@du.edu
WHERE & WHAT TO SUBMIT
Send the electronic version of the abstract before May 1,
2008 (June 15, 2008 for posters) as an e-mail attachment to
abstracts@rockychem.com.
Please put "50th RMC Abstract - (insert appropriate
symposia)" in the subject line.
Milestone Presentations, LLC
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